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Learn vocabulary, terms, and more with flashcards, games, and other study tools. As the single alone pair not counted in the shapes description, we can conclude that the molecular shape of SO2 is V-Shaped or Bent. Thus, the electron-pair geometry is tetrahedral and the molecular structure is bent with an angle slightly less than 109.5°. In essence the Valence Shell Electron Pairs are Repelling each other, giving SO2 it's shape. Oxygen atoms will come off each side of the sulfur. Alternatively, the electron geometry of sulphur dioxide is in the shape of a trigonal planar. The SO2 molecule is a bent molecule, existing as a resonance structure, with a lone pair of electrons on the S. The molecule has an S-O single bond and an S=O double bond. SO2 Electron Geometry The electron geometry of SO2 is formed in the shape of a trigonal planner. > a) "BrF"_5 The Lewis structure is The central "Br" atom has six electron domains, so the electron geometry is octahedral. It has four electron regions, but only two are filled by lone pairs. Seo2 Lewis Structure. Electron Geometry. Step 2: Apply the AXE VSEPR notation where:. The electron geometry gives the spatial arrangement of all the bonds and lone pairs of a molecule. b. Q: 14) Draw the correct product for the reaction below. window._wpemojiSettings = {"baseUrl":"https:\/\/s.w.org\/images\/core\/emoji\/2\/72x72\/","ext":".png","svgUrl":"https:\/\/s.w.org\/images\/core\/emoji\/2\/svg\/","svgExt":".svg","source":{"concatemoji":"http:\/\/www.canadian-horizons.ca\/wp-includes\/js\/wp-emoji-release.min.js?ver=4.6.20"}}; Equalizer Apo Earrape, 0 0. halogen. identify the bond hybridization for the bond marked for the AsF5 molecule on the right: σ: As(sp^3d)-F(p) This means that they exert their negative charge’s pressure in a broader area than the electrons shared with hydrogen, which squishes the … This is the simplest explanation of SO 3 electron geometry. 2 H2(g) + O2(g)  2 H2O(l) How many electron groups there are. Therefore this molecule is polar. It is determined by the central atom and the surrounding atoms and electron pairs. Step 3: Use the VSEPR table to determine the SO 2 electron geometry: … (hint=draw the lewis structure for NH3) eg=tetrahedral, mg=trigonal pyramidal, sp3. SO3 Trigonal Planar / Trigonal Planar CH2Cl2 Tetrahedral / Tetrahedral PH3 Tetrahedral / Trigonal Pyramidal CF4 Tetrahedral / Tetrahedral SH2 Tetrahedral / Bent SCl2 Tetrahedral / Bent The valence-shell electron-pair repulsion (VSEPR) model allows us to predict which of the possible structures is actually observed in most cases. SO2 Electron Geometry The electron geometry of SO2 is formed in the shape of a trigonal planner. Tetrahedral- CF4 Trigonal Pyramidal- NF3 Bent- OF2 and H2S. It can determine reactivity, polarity, color, attraction, biological activity, etc. b. trigonal pyramid molecular geometry. SO2 has a election domain geometry of trigonal planar because there are three election groups surrounding the oxygen atom, 2 groups for the sulfur atoms … Two oxygens form single bonds with sulfur, while one forms a double bond. The electron domain geometry refers to the number of electron groups around the central atom. 4 years ago. H2S is also a precursor for elemental Sulfur. Let's do another example of a molecule that has three electron clouds-- so in this case, sulfur dioxide. Therefore this molecule is polar. Equalizer Apo Earrape, Shed Roof Truss Calculator, Or if you need more Molecular vs Electron Geometry practice, you can also practice Molecular vs Electron Geometry practice problems. So three electron clouds. 120 degrees) with asymmetric charge distribution on the central atom. Answer to: Determine the following for SO2. The water molecule is bent molecular geometry because the lone electron pairs, although still exerting influence on the shape, are invisible when looking at molecular geometry. We don’t believe students should memorize these, but they should understand how to arrive at the different geometric shapes. Tetrahedral for all. give electron geometry (eg), molecular geometry (mg), and hybridization for NH3. What Is Birth Tourism, Once finding out, you will see that the AX2N2 has a ‘Bent Molecular Geometry.’ H2O, which is a three atom molecule, comes with the angular shape.. H2O Bond Angles. (1 corresponds to the largest bond angle) NO2 CO2 Н20 QUESTION 3 1 The Lewis structure of O2 contains a … Predict the central atom of the molecule. molecular shape with idealized QUESTION 2 1 Rank the following molecules by bond angle. SO3 has a central sulfur atom and three surrounding oxygens, with a total of 24 valence electrons. 120 degrees) with asymmetric charge distribution on the central atom. The S-O bonds are polar because oxygen is more electronegative than sulfur. The SO2 molecule is a bent molecule, existing as a resonance structure, with a lone pair of electrons on the S. The molecule has an S-O single bond and an S=O double bond. 4 0. lithgow. So, our first perception of the original structure does not match with the original one. The overall arrangement is trigonal planar. Chicken Potatoes Zucchini,  However, the vertical bond dipole has no opposing partner, so the molecule is polar. SO2 has a linear bond angles of 180 electron geometry and a 180 degrees. The electron domain geometry refers to the number of electron groups around the central atom. We don’t believe students should memorize these, but they should understand how to arrive at the different geometric shapes. 0 0. halogen. SO2 Electron Geometry The electron geometry of SO2 is formed in the shape of a trigonal planner. Sulfur will have two double bonds and a lone pair, for a total of 18 electrons. The ionization energy of disulfur dioxide is 9.93 ± 0.02 eV. Half-reaction SO 2 molecular geometry is considered to V-shaped or bent. Square pyramidal, 6 electron groups Place the following in order of increasing F-A-F bond angle, where A … © copyright 2003-2020 Study.com. 4 0. lithgow. All the very best! SO 2 is polar due to its geometry (angular) and the presence of a lone electron pair. The S-O bonds are polar because oxygen is more electronegative than sulfur. Moreover, experimental results show that the bond angle in SO{eq}_2 They have smaller bond angles compared to the 120 degrees bond angle in trigonal planar molecules. Question: The Molecule SO2 Has A: A. Trigonal Planar Electron Pair Geometry B. SO2 has a election domain geometry of trigonal planar because there are three election groups surrounding the oxygen atom, 2 groups for the sulfur atoms … Disulfur dioxide is also produced upon a microwave discharge in sulfur dioxide diluted in helium. - Definition & Process, UExcel Bioethics - Philosophical Issues: Study Guide & Test Prep, Alberta Education Diploma - Science 30: Exam Prep & Study Guide, Human Anatomy & Physiology: Help and Review, High School Biology: Homework Help Resource, UExcel Anatomy & Physiology: Study Guide & Test Prep, Prentice Hall Biology: Online Textbook Help, Holt Physical Science: Online Textbook Help, Prentice Hall Chemistry: Online Textbook Help, Biological and Biomedical The dot structure for sulfur dioxide has sulfur with a double bond to an oxygen on the left, and two lone pairs of electrons on that oxygen, and the sulfur with a double bond to an oxygen on the right, and two lone pairs of electrons on that oxygen. b. trigonal pyramid molecular geometry. Rapidly absorbs dry hydrogen fluoride , hydrogen chloride , hydrogen bromide to form the corresponding selenium oxohalide. Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO2. 120 degrees) with asymmetric charge distribution on the central atom. A good rule of thumb is to determine the electron geometry first then assume that any lone pairs of electrons are along the equator of the central atom. Also, the angular geometry of the H-C=C bond in ethylene is 121.3 degrees. As shown in the image above, there is one lone pair on sulfur while bonded to this atom is exactly two oxygen atoms, bound by double bonds. (adsbygoogle = window.adsbygoogle || []).push({});. {/eq}. Since sulfur element has 6 electrons in its outermost orbital after forming two double bonds with the oxygen atoms, there are 2 more electrons remaining; these can act as a lone electron pair. In fact, the bond angle is 104.5°. That makes three domains with electrons. Predict the molecular geometry of {eq}SO_2 4 years ago. Electronic Geometry, Molecular Shape, and Hybridization Page 1 The Valence Shell Electron Pair Repulsion Model (VSEPR Model) The guiding principle: Bonded atoms and unshared pairs of electrons about a central atom are as far from one another as possible. Since the difference in polarity is greater than zero, SO2 is a polar molecule. But ::O=S=O:: has only four valence electrons on sulfur. Shed Roof Truss Calculator, Then draw the 3D molecular structure using VSEPR rules: Decision: The molecular geometry of SO 2 is bent (approx. Answer: SO2 is a polar molecule because the lone pair of electrons on the central sulfur atom cause electron-electron repulsion that forces a bent structure leading to an unequal distribution of charge throughout the molecule. } Since sulfur element has 6 electrons in its outermost orbital after forming two double bonds with the oxygen atoms, there are 2 more electrons remaining; these can act as a lone electron pair. Step 1: Draw the Lewis structure for SO2 using the “easy” method where you calculate the total valence electrons in the molecule to determine the Lewis structure. Hybridization: sp 2. The three pairs of bonding electrons arranged in the plane at the angle of 120-degree. Learn vocabulary, terms, and more with flashcards, games, and other study tools. For the following molecules: 1) draw a Lewis Dot structure, including c... A: According to Q&A guidelines, I am allowed to answer only 3 sub-parts of multiple sub-parts in th... Q: Ethanol, C2H6O, is most often blended with gasoline - usually as a 10 percent mix - to create a fuel... A: Given: Heat of combustion of ethanol =  326.7 kcal/mol. Therefore this molecule is polar. Some background on VSEPR theory:  Valence Shell Electron Pair Repulsion Theory (VSEPR) suggests that molecular geometry is based purely on the number of atoms and lone pairs attached to a central atoms AND that electrostatic repulsions will place these atoms and lone pairs as far away from each other as geometrically possible. d. tetrahedral molecular geometry. And so you could think about those electron clouds repelling each other equally. The wide variety of different molecular structures depends on the number of atoms involved as well as the number of electron pairs, and these also determine the bond angles of the atoms. Sulfur in this molecule is hypervalent. CO2, SO2, NO2-Which of the statements is correct? c. bent 109 molecular geometry. Figure 1: Chemical Structure of SO2 draw the lewis dot diagram for H2S. A quick explanation of the molecular geometry of NO2 - (the Nitrite ion) including a description of the NO2 - bond angles. - Definition, Structure & Formula, Photochemical Smog: Definition, Formation & Effects, The Common Ion Effect and Selective Precipitation, What Is Glucose? 2 bonding regions and a lone pair. How to find the SO2 molecular geometry using VSEPR theory is not very difficult using these three steps. So the answer to the question is B. Minus..It is having a trigonal planar electron pair geometry with angles of 134• and Nitrogen has one electron extra on it after bonding with Oxygen atoms this makes it negatively charged.These are the structues that show its geometry. a. I've listed below what I think they are below. Two oxygens form single bonds with sulfur, while one forms a double bond. That’s it!!! - Definition, Structure & Formula, Photochemical Smog: Definition, Formation & Effects, The Common Ion Effect and Selective Precipitation, What Is Glucose? The electron geometry can be obtained using VSEPR theory. The electron geometry of SO2 is formed in the shape of a trigonal planner. https://www.khanacademy.org/.../v/more-on-the-dot-structure-for-sulfur-dioxide The 2 lone electron pairs exerts a little extra repulsion on the two bonding hydrogen atoms to create a slight compression to a 104 o bond angle. E° (V) Question: SO2 Has A Linear Bond Angles Of 180 Electron Geometry And A 180 Degrees. As the one pair remained alone, two double pairs are bonded and form a bent shape. - Definition & Process, UExcel Bioethics - Philosophical Issues: Study Guide & Test Prep, Alberta Education Diploma - Science 30: Exam Prep & Study Guide, Human Anatomy & Physiology: Help and Review, High School Biology: Homework Help Resource, UExcel Anatomy & Physiology: Study Guide & Test Prep, Prentice Hall Biology: Online Textbook Help, Holt Physical Science: Online Textbook Help, Prentice Hall Chemistry: Online Textbook Help, Biological and Biomedical The dot structure for sulfur dioxide has sulfur with a double bond to an oxygen on the left, and two lone pairs of electrons on that oxygen, and the sulfur with a double bond to an oxygen on the right, and two lone pairs of electrons on that oxygen. Minus..It is having a trigonal planar electron pair geometry with angles of 134• and Nitrogen has one electron extra on it after bonding with Oxygen atoms this makes it negatively charged.These are the structues that show its geometry. Two oxygens form single bonds with sulfur, while one forms a double bond. b. linear molecular geometry. Also, I have mentioned some of the best usages of Sulfur Hexafluoride to help you know more about it. Transcript: Hi, this is Dr. B. - Structure, Uses & Formula, Extraction of Aluminum, Copper, Zinc & Iron, What is Sodium Chloride? Some of the most common shapes tha… The molecular geometry is square pyramidal. To predict the molecular geometry of sulfur dioxide (SO{eq}_2 {/eq}), what we need to do is draw the Lewis structure of this compound. All rights reserved. The molecular geometry is the shape of the molecule. Therefore this molecule is polar. - Definition, Structure & Formula, Photochemical Smog: Definition, Formation & Effects, The Common Ion Effect and Selective Precipitation, What Is Glucose? Why the dipole moment of so2 is not zero? As the one pair remained alone, two double pairs are bonded and form a bent shape. b. trigonal pyramid molecular geometry. Thus, the electron-pair geometry is tetrahedral and the molecular structure is bent with an angle slightly less than 109.5°. The geometry of the molecule can be described in two ways: 1) Electron Geometry–the geometry that takes lone pairs and atoms into account (hint: there is are only 5 different electron geometries) and 2) Molecular Geometry– the geometry that ignores lone pairs and only takes atoms into account (there are 13 of these). However, the vertical bond dipole has no opposing partner, so the molecule is polar. - Definition, Formula & Uses, Working Scholars® Bringing Tuition-Free College to the Community. Figure 1: Chemical Structure of SO2 A=Number of central atoms X=Number of surrounding atoms E= Number of lone pairs on central atom. electron geometry, molecular geometry and polarity of N2O (N central)? Figure \(\PageIndex{9}\): (a) H 2 O has four regions of electron density around the central atom, so it has a tetrahedral electron-pair geometry. Since sulfur element has 6 electrons in its outermost orbital after forming two double bonds with the oxygen atoms, there are 2 more electrons remaining; these can act as a lone electron pair. All rights reserved. A is the central atom, the Sulfur, we have one of those, X the bonded atoms, those two oxygen atoms, and N that is the unbonded electron pairs. All the very best! SO 2 molecular geometry is considered to V-shaped or bent. b. linear molecular geometry. Disulfur dioxide is also produced upon a microwave discharge in sulfur dioxide diluted in helium. b. linear molecular geometry. As the single alone pair not counted in the shapes description, we can conclude that the molecular shape of SO2 is V-Shaped or Bent. To predict the molecular geometry of sulfur dioxide (SO{eq}_2 {/eq}), what we need to do is draw the Lewis structure of this compound. There is no charge on the m There are two electron domains around the central carbon atom, therefore it is linear (Niles, 2004). We will put these electrons on the atom of Sulphur.The SO2 has a bond angle of 120-degree. Two double pairs are bonded together and there is one lone pair as well which further gives it a bent shape. It is not perfectly 109.5° because lone pairs are less constrained in where they can go than shared electrons. Lv 4. The S-O bonds are polar because oxygen is more electronegative than sulfur. Then draw the 3D molecular structure using VSEPR rules: Decision: The molecular geometry of SO 2 is bent (approx. We all know that it is the formula of water and also one of the most well-known, common chemical recipes. - Structure, Uses & Formula, Extraction of Aluminum, Copper, Zinc & Iron, What is Sodium Chloride? You were asked for the 'electron geometry' so 'Trigonal Planer' is the answer and not Bent/Angular which is the 'molecular geometry' (shape) of the molecule. Minus..It is having a trigonal planar electron pair geometry with angles of 134• and Nitrogen has one electron extra on it after bonding with Oxygen atoms this makes it negatively charged.These are the structues that show its geometry. Well, how many valence electrons do we consider …. You can look at the atoms like puzzle pieces where you are trying to fit together the electrons so that everyone that needs an octet has one. For homework help in math, chemistry, and physics: www.tutor-homework.com. Check the post here to know about the SF6 molecular geometry and how to draw lewis structure of SF6. The water molecule is bent molecular geometry because the lone electron pairs, although still exerting influence on the shape, are invisible when looking at molecular geometry. The shape of most molecules can be predicted using the Valence Shell Electron Pair Repulsion (VSEPR) method. The molecular geometry is the shape of the molecule. This may not be the best structure. display: inline !important; 0 0. halogen. - Definition, Structure & Formula, What is Carbon Dioxide? So, the number of remained valence electrons are 18-16 = 2. Sulfur in this molecule is hypervalent. Sulfur dioxide has a total of 18 valence electrons, with six electrons contributed by each of the atoms in the compound. 4 0. lithgow. And then we have a lone pair of electrons … So sulfur dioxide, let's count up the number of valence electrons. All the "Br-F" bonds are polar, The two opposing pairs in the horizontal plane cancel each other. This is because it has 3 electron domains - the 6 valence electrons for sulfur form 2 single bonds with 2 oxygen atoms and sulfur has one non-bonding lone pair. In order to determine the molecular geometry for H2O, observe the Lewis structure of the same. Here, you will find details like the shape of Sulfur Hexafluoride and whether the SF6 molecule is polar or nonpolar. May 9, 2017. As a result, the remaining two are shared with two hydrogens (one each). Question: The Molecule SO2 Has A: A. Trigonal Planar Electron Pair Geometry B. So the answer to the question is B. b. linear molecular geometry. Two oxygens form single bonds with sulfur, while one forms a double bond. Step 3: Use the VSEPR table to determine the SO 2 electron geometry: … (hint=draw the lewis structure for NH3) eg=tetrahedral, mg=trigonal pyramidal, sp3. What Is Birth Tourism, The following are the steps used in this determination. Table 10.2 Examples : In sulphur dioxide molecule there are three electron pairs on the S atom. All the "Br-F" bonds are polar, The two opposing pairs in the horizontal plane cancel each other. Q: what is the name of the function group for both? As you may know, I have already explained about the molecular shape of CO2, SO2, SO3, SF4, and XeF4. The three pairs of bonding electrons arranged in the plane at the angle of 120-degree. A frequently asked question with VSEPR is whether or not a student should memorize the different molecular geometries an atom could take. Here, you will find details like the shape of Sulfur Hexafluoride and whether the SF6 molecule is polar or nonpolar. 4 electrons of sulfur bond with the two pairs of both oxygen atoms around sulfur. SO3 has a central sulfur atom and three surrounding oxygens, with a total of 24 valence electrons. Lewis electron structures give no information about molecular geometry, the arrangement of bonded atoms in a molecule or polyatomic ion, which is crucial to understanding the chemistry of a molecule. But ::O=S=O:: has only four valence electrons on sulfur. You can look at the atoms like puzzle pieces where you are trying to fit together the electrons so that everyone that needs an octet has one. Start studying Ch.10 Electron Geometry. The most common technology for capturing sulfur... How could I produce sulfuric acid at home? The only one that has 4 electron pairs around the central atom is SnCl3-, so it is the one with an electron geometry … It can hold more than 8 electrons. Molecular geometry is the way atoms are arranged in a molecule.The three-dimensional arrangement determines many properties of that molecule. . " /> Stable to light and heat. SO2 has a election domain geometry of trigonal planar because there are three election groups surrounding the oxygen atom, 2 groups for the sulfur atoms … Two oxygens form single bonds with sulfur, while one forms a double bond. The rat... Q: F The electron geometry of SO2 is formed in the shape of a trigonal planner. The molecules SeS3, SeS2, PCl5, TeCl4, ICl3, and XeCl2 all exhibit at least one bond angle which is approximately 120 degrees. The three pairs of bonding electrons arranged in the plane at the angle of 120-degree. Step 3: Use the VSEPR table to determine the SO2 electron geometry: three substituents is trigonal planar. Here's what I get. SO3 has a central sulfur atom and three surrounding oxygens, with a total of 24 valence electrons. The initial te... *Response times vary by subject and question complexity. With no lone pair repulsions, we do not expect any bond angles to deviate from the ideal. img.wp-smiley, 1. The three pairs of bonding electrons arranged in the plane at the angle of 120-degree. Hence, Electron Domain theory accounts for the geometry of \(\ce{PCl_5}\). So we have a trigonal planar geometry with a bond angle of 120 degrees. The following are the steps used in this determination. The bond angle in SO2 … The molecule is trigonal planar because there are three electron domains around the central sulfur atom. Sulfur Dioxide on Wikipedia . SO 2 is polar due to its geometry (angular) and the presence of a lone electron pair. Summary – SO2 vs SO3 SO 2 … Examples: Use the electron geometry table to determine the steric number and electron geometry of each molecule. In fact, the bond angle is 104.5°. Figure \(\PageIndex{9}\): (a) H 2 O has four regions of electron density around the central atom, so it has a tetrahedral electron-pair geometry. The molecular geometry is square pyramidal. Gatorade Cookies And Cream Protein Powder, molecular shape with idealized QUESTION 2 1 Rank the following molecules by bond angle. Thank you so much!!!! width: 1em !important; One of the examples of molecule with linear shape of molecule is carbon dioxide or CO2. - Definition & Explanation, What is Silica? Services, What is Sulfur Dioxide? We only have one unbonded electron pair for SO2. box-shadow: none !important; CO2, SO2, NO2-Which of the statements is correct? Lewis electron structures give no information about molecular geometry, the arrangement of bonded atoms in a molecule or polyatomic ion, which is crucial to understanding the chemistry of a molecule. Then draw the 3D molecular structure using VSEPR rules: Decision: The molecular geometry of SO 2 is bent (approx. Any of the other molecular geometries (except square planar and linear) under the box will be polar. Sulfur Dioxide on Wikipedia. Based on the Lewis structure above the AXE notation would be AX2E1, meaning there are a total of three substituents (2 atoms and 1 lone pair ) coming off of the central atom. Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO2. Let's do another example of a molecule that has three electron clouds-- so in this case, sulfur dioxide. a. a. Electron geometry b. Molecular geometry (shape) c. Is the molecule symmetrical or asymmetrical? It is determined by the central atom and the surrounding atoms and electron pairs. {/eq}), what we need to do is draw the Lewis structure of this compound. Looking at the table, when we go from AX2, AX3 and all the way down to AX2N2, we will find out that the bond angle is … While the electron geometry is trigonal planar, the SO2 molecular geometry is bent. Lewis structure is the structural representation of the number of valence electrons that participate in the bond formation and nonbonding electron pairs. Tetrahedral for all. The 2 lone electron pairs exerts a little extra repulsion on the two bonding hydrogen atoms to create a slight compression to a 104 o bond angle. Molecular geometry is the 3-dimensional shape that a molecule occupies in space. Step 2: Apply the AXE VSEPR notation where:. For homework help in math, chemistry, and physics: www.tutor-homework.com. Thus, the electron-pair geometry is tetrahedral and the molecular structure is bent with an angle slightly less than 109.5°. As a result, the remaining two are shared with two hydrogens (one each). Which of the statements below is true for the Lewis structure of the SO2 molecule? So, our first perception of the original structure does not match with the original one. (1 corresponds to the largest bond angle) NO2 CO2 Н20 QUESTION 3 1 The Lewis structure of O2 contains a … Predict the central atom of the molecule. The most common technology for capturing sulfur... How could I produce sulfuric acid at home? It has four electron regions, but only two are filled by lone pairs. Therefore this molecule is polar. 6 Mozzarella Sticks Carbs, The S-O bonds are polar because oxygen is more electronegative than sulfur. Disulfur dioxide is formed transiently when hydrogen sulfide and oxygen undergo flash photolysis. - Definition & Explanation, What is Silica? At a pressure of 0.1 mmHg (13 Pa), five percent of the result is S 2 O 2. same electronic geometry given at the top of the column. So the answer to the question is B. As the single alone pair not counted in the shapes description, we can conclude that the molecular shape of SO2 is V-Shaped or Bent. In this example, sulfur is the central atom. Here, we have explained the molecular geometry, electron geometry, Lewis structure, bond angle, and polarity of SO2 (Sulfur Dioxide). For each oxygen to have an octet, there must be double bonds between the sulfur and oxygen atoms  (For VSEPR purposes, we can ignore the lone pairs coming off of oxygen). Unlike CO2, the molecular geometry of SO2 is bent rather than linear, giving SO2 a net dipole moment. The valence-shell electron-pair repulsion (VSEPR) model allows us to predict which of the possible structures is actually observed in most cases. Back to Molecular Geometries & Polarity Tutorial: Molecular Geometry & Polarity Tutorial. Molecules with a bent shape or geometry have an electron pair geometry of trigonal planar. May 9, 2017. 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